Process Technology for Production of Hydrogen-Rich Water and Water Characterizing by Highly Negative Oxidation Reduction Potential
Asian Journal of Applied Chemistry Research,
Page 41-55
DOI:
10.9734/ajacr/2022/v12i1214
Abstract
The construction of plasma reactors and the technological process of obtaining water rich in hydrogen and characterized by a negative oxidation potential are presented in the publication. Hydrogen-rich water was obtained based on non-plasma technology and water saturation with hydrogen gas in a reactor vessel or in glass bottles. We have developed a plasma flow reactor that allows for contactless microstructuring and modifying the properties of water / aqueous solutions by resonant stochastic vibration amplification of selected chemical compounds in water with broadband electromagnetic noise with frequencies ranging from 100 Hz to 50 MHz generated during plasma discharge. This water is then saturated with hydrogen gas in the reactor or in glass bottles. The water obtained in the reactor is characterized by a high concentration of hydrogen (8 mg/L) and a negative oxidation-reduction potential (ORP) value (-450 mV). In this technology, the process of saturating water with hydrogen in a 1 m3 tank at a temperature of 20oC takes about 30 minutes. In the technology of obtaining water with negative ORP potential in the bottles, the process of saturating the water with hydrogen lasts only 5-10 seconds. Water obtained with such technology in the glass bottles does not contain much hydrogen gas after 24 hours, while it is characterized by a negative ORP value of about -380 mV even for a period of three months. Obtaining water with presented parameters is possible only in the case of water subjected to the influence of broadband electromagnetic noise with frequencies ranging from 100 Hz to 50 MHz generated during plasma discharge.
Keywords:
- Hydrogen-rich water (HRW)
- stochastic liquid softener system for water
- hydrogen concentration in water
- oxidation reduction potential (ORP)
How to Cite
Reszke, E., Binkiewicz, G., & Schroeder, G. (2022). Process Technology for Production of Hydrogen-Rich Water and Water Characterizing by Highly Negative Oxidation Reduction Potential. Asian Journal of Applied Chemistry Research, 12(1), 41-55. https://doi.org/10.9734/ajacr/2022/v12i1214
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DOI: 10.1016/S1385-8947(02)00015-3
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Kim JJ, Yu AR, Park GS, Park SK, Jang HD, Yang HJ, Lee MY. Development of hybrid-reduced water and its antioxidative effects. Toxicol Environ Health Sci. 2011;3;327–231.
DOI: 10.1007/s13530-011-0104-3
Lapin AA, Kalayda AA, Filippov SD, Zelenkov VN. 2019 IOP Conf. Ser.: Earth Environ Sci. 288 012054.
Patent RF2557974. A61Р43, А61K33 Hydrogen cocktail - a means to stimulate lymphatic drainage, the way it is produced.
Patent PL 238174. Method and device for microstructuring of liquids, including body fluids.
Tanaka Y, Teraoka F, Nakagawa M, Miwa N. Dependencies of hydrogen-water on mineral-based hardness, temperatures and the container materials, and effects of the oral washing and drinking. Med Gas Res. 2020;10;67-74.
DOI: 10.4103/2045-9912.285559
DOI: 10.1007/s13530-011-0104-3
Sim M, Kim CS, Shon WJ, Lee YK, Choi EY, Shin DM. Hydrogen-rich water reduces inflammatory responses and prevents apoptosis of peripheral blood cells in healthy adults: A randomized, double-blind, controlled trial. Sci Rep. 2020;10;12130.
DOI: 10.1038/s41598-020-68930-2
Ostojic SM. Hydrogen-rich water as a modulator of gut microbiota? J Functional Foods. 2021;78;104360.
Available:https://doi.org/10.1016/j.jff.2021.104360
An R, Luo S, Zhou H, Zhang Y, Zhang L, Hu H, Li P. Effects of hydrogen-rich water combined with vacuum precooling on the senescence and antioxidant capacity of pakchoi (Brassica rapa subsp. Chinensis). Scientia Horticulturae. 2021;289;110469.
DOI: 10.1016/j.scienta.2021.110469
Vazquez D, Guillen-Gosalbez G. Process design within planetary boundaries: Application to CO2 based methanol production. Engineering Science 2021;246; 116891.
DOI: 10.1016/j.ces.2021.116891
Khunathorncharoenwong N, Charoensuppanimit P, Assabumrungrat S, Kim-Lohsoontorn P. Techno-economic analysis of alternative processes for alcohol-assisted methanol synthesis from carbon dioxide and hydrogen. Ind Eng Chem Res. 2021;46;24591-24606.
DOI: 10.1016/j.ijhydene.2020.01.230
Lu C, Zhang Z, Zhou X, Hu J, Ge X, Xia C, et al. Effect of substrate concentration on hydrogen production by photo-fermentation in the pilot-scale baffled bioreactor. Bioresource Technology 2018;247; 1173–1176.
DOI: 10.1016/j.biortech.2017.07.122
Liu Y, Zhang Y, Wang T, Tsubaki N. Efficient conversion of carbon dioxide to methanol using copper catalyst by a new low-temperature hydrogenation process. Chem Lett. 2007;36;1182–1183.
DOI: 10.1246/cl.2007.1182
Jadhav SG, Vaidya PD, Bhanage BM, Joshi JB. Catalytic carbon dioxide hydrogenation to methanol: A review of recent studies. Chem Eng Res Des. 2014;92;2557–2567.
DOI: 10.1016/j.cherd.2014.03.005
Boretti A. Renewable hydrogen to recycle CO2 to methanol, Int. J. Hydrogen Energy. 2013;38;1806 -1812.
DOI: 10.1016/j.ijhydene.2012.11.097
Mao WL, Mao HK. Hydrogen storage in molecular compounds., PNAS. 2004;101;708–710.
DOI: 10.1073/pnas.0307449100
Timon R, Olcina G, Gonzalez-Custodio A, Camacho-Cardenosa M, Camacho-Cardenosa A, Guardado IM. Effects of 7-day intake of hydrogen-rich water on physical performance of trained and untrained subjects. Biol Sport. 2021; 38;269–275.
DOI: 10.5114/biolsport.2020.9862
Lapin AA, Kalayda AA, Filippov SD, Zelenkov VN. Biochemical effects of molecular hydrogen in aqueous systems International Scientific and Practical Conference: Water Power Energy Forum 2018IOP Conf. Series: Earth and Environmental Science. 2019;288: 012054IOP.
Shen M, Zhang H, Yu C, Wang F, Sun X. A review of experimental studies of hydrogen asa new therapeutic agent in emergency and critical care medicine, Med Gas Res. 2014;4;17.
DOI: 10.1186/2045-9912-4-17
Tanaka Y, Teraoka F, Nakagawa M, Miwa N. Dependencies of hydrogen-water on mineral-based hardness, temperatures and the container materials, and effects of the oral washing and drinking. Med Gas Res. 2020;10:67-74.
DOI: 10.4103/2045-9912.285559
Engineering Tool Box, Solubility of Gases in Water vs. Temperature.
Available:https://www.engineeringtoolbox.com/gases-solubility-water-d_1148.html
Wiebe R, Gaddy VL. The Solubility of Hydrogen in Water at 0, 50, 75 and 100° from 25 to 1000 Atmospheres. J Am Chem Soc. 1934;56:76–79.
Available:https://doi.org/10.1021/ja01316a022
Wiebe R, Gaddy VL, Heins JC. Solubility of hydrogen in sodium chloride brine at high pressures. Ind Eng Chem. 1932;24: 823-825.
DOI: 10.1016/j.fluid.2021.113025
Kling G, Maurer G. The solubility of hydrogen in water and in 2-aminoethanol at temperatures between 323 K and 423 K and pressures up to 16 MPa. J Chem Thermodyn. 1991;23:531-541.
DOI:10.1016/S0021-9614(05)80095-3
Gillespie PRC, Wilson GM. Vapor-liquid equilibrium data on water-substitute gas components: N2 - H2O, H2 - H2O, CO - H2O, H2 - CO - H2O, and H2S - H2O. GPA Research Report. 1980;1-34.
Rahbari A, Brenkman J, Hens R, Ramdin M, van den Broeke LJP, Schoon R, et al. Solubility of water in hydrogen at high pressures: A molecular simulation study. J Chem Eng Data. 2019;64;4103−4115.
DOI: 10.1021/acs.jced.9b00513
Sabo D, Rempe SB, Greathouse JA, Martin MG. Molecular studies of the structural properties of hydrogen gas in bulk water, Molecular studies of the structural properties of hydrogen gas in bulk water. Molecular Simulation. 2006; 32;269–278.
DOI: 10.1080/08927020600728621
Vos WL, Finger LW, Hemley RJ, Mao HK. Novel H2-H20 clathrates at high pressures. Phys Rev Lett. 1993;71;3150- 3153.
DOI:10.1103/PhysRevLett.71.3150.
Mao WL, Mao HK, Hydrogen storage in molecular compounds. PNAS. 2004;101;708–710.
Available:doi10.1073pnas.0307449100
Sadlej J, Cybulski SM, Szczȩśniak MM. Ab initio study of nonadditive effects in the (H2O)2•H2 Cluster, Phys. Chem. 1996;100;10875–10881.
Available:https://doi.org/10.1021/jp952781+
Sabo D, Varma S, Martin MG, Rempe SB. Studies of the thermodynamic properties of hydrogen gas in bulk water. J Phys Chem B. 2008;112;867-876.
DOI: 10.1021/jp075459v
Kampbell DH, Wilson JT, McInnes DM. Determining dissolved hydrogen, methane, and vinyl chloride concentrations in aqueous solution on a nanomolar scale with the bubble strip method. Proceedings of the 1998 Conference on Hazardous Waste Research.
Available:https://engg.ksu.edu/HSRC/98Proceed/15Kampbell/15kampbell.pdf
Goncharuk VV, Bagrii VA, Melnik LA, Chebotareva RD, Bashtan SY. The Use of Redox Potential in Water Treatment Processes. J Water Chem Technol. 2010;32;1–9.
DOI: 10.3103/S1063455X10010017
Oxidation Reduction Potential (ORP) International Hydrogen Standards Association.
Available:https://www.intlhsa.org/oxidation-reduction-potential-orp/
Sharpe R. Analysis of the relationship between dissolved molecular hydrogen gas, pH and ORP using the nernst equation.
Available:https://nebula.wsimg.com/e00f13c6a421e24d28be6558ff968736?AccessKeyId=781CCB9A394A3C0D544A&disposition=0&alloworigin=1
Miyahara T, Oizumi M, Nakatani T, Sato T. Effect of voltage polarity on oxidation-reduction potential by plasma in water. AIP Advances. 2014;4;047115.
Available:https://doi.org/10.1063/1.4871475
Chang CN, Ma YS, Lo CW. Application of oxidation–reduction potential as a controlling parameter in waste activated sludge hydrolysis. Chemical Engineering Journal 2002;90;273–281.
DOI: 10.1016/S1385-8947(02)00015-3
Ohsawa I, Ishikawa M, Takahashi K, Watanabe M, Nishimaki K, Yamagata K, et al. Hydrogen acts as a therapeutic antioxidant by selectively reducing cytotoxic oxygen radicals. Nat Med. 2007;13;688–694.
DOI: 10.1038/nm1577
Yelkin I, Reszke E, Schroeder G. Glow discharge plasma as a cause of changes in aqueous solutions: The mass spectrometry study of solvation processes of ions. Asian J Chem. 2021;33;220-230.
DOI:10.14233/ajchem.2021.2301
Yelkin I, Reszke E, Binkiewicz G, Schroeder G. The industrial production of water dedicated to absorption of gases. Journal of Water Resource and Protection. 2021;13;632-653.
DOI: 10.4236/jwarp.2021.138034
Seo T, Kurokawa R, Sato B. A convenient method for determining the concentration of hydrogen in water: use of methylene blue with colloidal platinum. Medical Gas Research 2012;2;1.
Available:http://www.medicalgasresearch.com/content/2/1/1
Hadjadj R, Csizmadia IG, Mizsey P, Jensen SK, Viskolcz B, Fiser B. Water enhanced mechanism for CO2 – Methanol conversion. Chem Phys Letters. 2020;746;137298.
DOI:10.1016/j.cplett.2020.137298
Davoodabadi A, Mahmoudi A, Ghasemi H. The potential of hydrogen hydrate as a future hydrogen storage medium. Science. 2021;24;101907.
DOI: 10.1016/j.isci.2020.101907
Tanaka Y, Teraoka F, Nakagawa M, Miwa N. Dependencies of hydrogen-water on mineral-basedhardness, temperatures and the container materials, and effects of the oral washing and drinking. Med Gas Res. 2020;10;67-74.
DOI: 10.4103/2045-9912.285559.
Russell G, Nenov A, Kisher H, Hancock JT. Molecular Hydrogen as Medicine: An Assessment of Administration Methods. Hydrogen. 2021;2;444–460.
Available:https://doi.org/10.3390/hydrogen2040025
Patent PL 405260. Method and device for antioxidant production drinking water enriched with active hydrogen.
Patent US10953041. Hydrogen-containing composition.
Patent CN209348450. A device for producing hydrogen-rich water with an ejector.
Patent CN110482667. A method of producing hydrogen-rich water by physical method and a device for it production.
Patent CN107021556. Apparatus and method of automatic production of high concentration water rich in hydrogen.
Kim JJ, Yu AR, Park GS, Park SK, Jang HD, Yang HJ, Lee MY. Development of hybrid-reduced water and its antioxidative effects. Toxicol Environ Health Sci. 2011;3;327–231.
DOI: 10.1007/s13530-011-0104-3
Lapin AA, Kalayda AA, Filippov SD, Zelenkov VN. 2019 IOP Conf. Ser.: Earth Environ Sci. 288 012054.
Patent RF2557974. A61Р43, А61K33 Hydrogen cocktail - a means to stimulate lymphatic drainage, the way it is produced.
Patent PL 238174. Method and device for microstructuring of liquids, including body fluids.
Tanaka Y, Teraoka F, Nakagawa M, Miwa N. Dependencies of hydrogen-water on mineral-based hardness, temperatures and the container materials, and effects of the oral washing and drinking. Med Gas Res. 2020;10;67-74.
DOI: 10.4103/2045-9912.285559
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